Study on Cation-Exchange of Removal Metallic Ions at PPy/PVS Film Manuscript Received: 20 March 2024, Accepted: 13 June 2024, Published: 15 September 2024, ORCiD: 0000-0003-4712-4847, https://doi.org/10.33093/jetap.2024.6.2.13

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Article
Published: Sep 15, 2024
DOI: https://doi.org/10.33093/jetap.2024.6.2.13
Keywords:
PPy/PSS, ESCA, Cation-exchange, Potential step method, Heavy metals

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Lay Lian Teo
Faculty of Information and Technology, Multimedia University, Melaka, Malaysia.

Abstract

Due to the presence of heavy metals in wastewater treatment and manufacturing water purification processes in industries, investigations into potential methods have been widely conducted. In this paper, we report the incorporation of cation-exchange for removing heavy metals from aqueous solutions. We further investigated the properties cation-exchange using potential step method on PPy/PVS film at titanium electrode. Satisfactory results have been obtained with the small scale of experimental. It was found that the PPy/PVS film is able to remove heavy metal ions such as copper, nickel, and cobalt at very low concentrations, less than or equal to 10 mg/L, reducing them to approximately 1 mg/L. The Leica Q500MC Image Processing and Analysis system displayed the uneven deposition of heavy metal ions on the surface of PPy/PVS. Furthermore, Electron Spectroscopy for Chemical Analysis (ESCA) demonstrated the deposition of heavy metals on the PPy/PVS film.

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Vol. 6 No. 2 (2024): https://doi.org/10.33093/jetap.2024.6.2
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References

S. Maity , A. Dubey and S. Chakraborty, “A Review on Polypyrrole-Coated Bio-Composites for The Removal of Heavy Metal Traces from Waste Water,” J. Indust. Textil., vol. 51, no. 1, pp. 152-173, 2021.

N. M. E. M. Habibun, H. A. K. Obidul and Y. Rosiyah, “The Removal of Heavy Metal Ions From Wastewater/Aqueous Solution using Polypyrrole-Based Adsorbents: A Review,” RSC Adv., vol. 6, pp. 14778-14791, 2016.

J. Bak, W. S. Chmiel, M. Gajewska, P. Malinowska and D. Kolodynska, “Determination of the Ni(II) Ions Sorption Mechanism on Dowex PSR2 and Dowex PSR3 Ion Exchangers Based on Spectroscopic Studies,” Materials, vol. 16, no. 2, pp. 644, 2023.

M. Arbabi, S. Hemati and M. Amiri, “Removal of Lead Ions from Industrial Wastewater: A Review of Removal Methods,” Int. J. Epidemiol Res., vol. 2, pp. 105–109, 2015.

G. Hu, J. Li and H. Hou, “A Combination of Solvent Extraction and Freeze Thaw for Oil Recovery from Petroleum Refinery Wastewater Treatment Pond Sludge,” J. of Hazard. Mater., vol. 283, pp. 832-840, 2015.

M. J. Iqbal, M. Z. Iqbal and A. Fazal, “Graphene/Polymer Composite Application on Supercapacitors,” Innovations in Graphene-Based Polymer Composites, Woodhead Publishing, pp. 583-610, 2022.

L. Hao, C. Dong, L. Zhang, K. Zhu and D. Yu, “Polypyrrole Nanomaterials: Structure, Preparation and Application,” Polymers, vol. 14, no. 23, pp. 5139, 2022.

S. S. Hossain, A. F. A. Rahman, A. Arsad, A. Basu, A. L. Pang, Z. Harun, M. M. A. Alwi and S. S. Ali, “Effect of Ultrasonication Parameters on the Structural, Morphological, and Electrical Properties of Polypyrrole Nanoparticles and Optimization by Response Surface Methodology,” Polymers, vol. 15, no. 6, pp. 1528, 2023.

L. Wang, H. Wu, X. Zhai, J. Shi, Q. Zhou, H. Li and J. Wan, “Ti3C2Tx MXene/Dopamine-modified Polypyrrole Flexible Composite Electrodes with Application in Energy Storage Devices,” J. Alloys and Compound., vol. 946, pp. 169347, 2023.

X. Zhang, X. Tan, P. Wang and J. Qin, “Application of Polypyrrole-Based Electrochemical Biosensor for the Early Diagnosis of Colorectal Cancer”, Nanomaterials, vol. 13, no. 4, pp. 674, 2023.

W. Li, Z. Yao, S. Zhang, X. Wang, X. Xia, C. Gu and J. Tu, “High-performance Na3V2(PO4)2F2.5O0.5 Cathode: Hybrid Reaction Mechanism Study via ex-situ XRD and Sodium Storage Properties in Solid-State Batteries,” Chem. Eng. J., vol. 423, pp. 130310, 2021.

S. El-Hanboushy, A. M. Mahmoud, Y. M. Fayez, H. M. Lotfy, M. Abdelkawy and H. M. Marzouk, “Design of Green Polypyrrole-based Solid-contact Ion-selective Sensors for Determination of Antihypertensive Drugs in Combined Dosage Forms and Spiked Human Plasma,” J. Electrochem. Soc., vol. 170, pp. 037520, 2023.

C. Weidlich, K.-M, Mangold and K. Juttner, “Conducting Polymers As Ion-Exchangers for Water Purification,” vol. 47, no. 5, pp. 741-745, 2001.

N. Kansara, L. Bhati, M. Narang and R. Vaishnavi, “Wastewater Treatment by Ion Exchange Method: A Review of Past and Recent Researches,” Environ. Sci.: An Indian J., vol. 12, no. 4, pp. 143-150, 2016.

J. M. Costa, “Considerations on Electrochemical Technologies for Water Purification and Wastewater Treatment,” Int. J. Environ. Res. Public Health, vol. 20, no. 12, pp. 6140, 2023.

T. Wang, H. Gang, Y. Cao, L. Yan, D. Wei, H. Wang and J. Zhang, “Hydrous CeO2 Polypyrrole Nanocomposite As A Stable and Efficient Adsorbent for Defluoridation of Acidic Wastewater,” J. Mater. Sci., vol. 58, pp. 7895–7914, 2023.

L. L. Teo, S. L. Sin and C. Y. Chan, “ESCA And TOF-SIMS Study on Oxidised and Reduced Polypyrrole-Poly (Vinylsulfonic Acid, Sodium Salt) Films Synthesized on Ti Electrodes,” J. Nanomater., vol. 2010, pp. 1-10, 2010.

F. A. Cotton, G. Wilkinson, Adv. Inorg. Chem., A Comprehensive Text, Third Edition, J. Chem. Educ., pp. 874-916, 1962.

D. Thomas, F. P. Andrew and M. A. S. Peter, “Dissolution and Passivation of Nickel. An X-Ray Photoelectron Spectroscopic Study”, J. Chem. Soc., Faraday Trans. 1, vol. 73, pp. 327-343, 1977.

G. Brauer, Handbook of Preparative Inorganic Chemistry, vol. 2, Second Edition, Academic Press, pp. 1012-1548, 1965.

C. W. Wood and A. K. Holliday, Modern Inorganic Chemistry, An Intermediate Text, Butterworths, pp. 357-358, 1967.

J. Kleinberg, W. J. Argersinger and E. Griswold, Inorganic Chemistry, D.C. Heath and Co., pp. 553-559, 1960.

A. Amri, Z. T. Jiang, C. Y. Yin, A Fadli, M. M. Rahman, S Bahri, H. Widjaja, N. Mondinos, T. Herawan, M. Munir and G. Priyotomo, “Structural, Optical, and Mechanical Properties of Cobalt Copper Oxide Coatings Synthesized from Low Concentrations of Sol–gel Process,” Phys. Stat. Solid. (a), vol. 213, no. 12, pp. 3205-3213, 2016.

C. D. Wagner, W. Riggs, L. Davis and J. Moulder, Handbook of X-ray Photoelectron Spectroscopy, Perkin-Elmer Corp., pp. 82-87, 1979.

C. D. Wagner, D. A. Zatko and R. H. Raymond, “Use of the Oxygen KLL Auger Lines in Identification of Surface Chemical States by Electron Spectroscopy for Chemical Analysis,” Anal. Chem., vol. 52, pp. 1445-1451, 1980.

G. Schon and S. T. Lundin, “ESCA Studies of Oxygen Adsorption on Nickel,” J. Elec. Spec. & Rel. Phen., vol. 1, pp. 105-109, 1972.

K. W. Wulser and M. A. Langell, “Methanol Adsorption on Single Crystal NiO (100) Studied by HREELS Deconvolution,” J. Elec. Spec. & Rel. Phen., vol. 59, pp. 223-241, 1992.